Product ID:83996, Q5119, SHELLSOL W HT
MSDS Date:06/05/2000
FSC:6810
NIIN:00-238-8119
Status Code:A
MSDS Number: CKXFL

Emergency Phone: 800-424-9300

Info Phone: 713-241-4819

Cage: TO094

Telephone: 713-241-4819

Cage: TO094

SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC

CAS: 64742-89-8

LD50 LC50 Mixture:ORAL LD50(RAT): >7.1G/KG NAPHTHA
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: MAY CAUSE TEMPORARY DISCOMFORT OR
IRRITATION TO THE EYES. SKIN: MAY BE SLIGHTLY IRRITATING TO THE
SKIN. PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE DEFATTING &
DRYING OF THE SKIN. INGESTION: LI QUID CAN DIRECTLY ENTER THE LUNGS
(ASPIRATION) WHEN SWALLOWED OR VOMITED. SERIOUS LUNG DAMAGE AND
POSSIBLY FATAL CHEMICAL PNEUMONIA (CHEMICAL PNEUMONITIS) CAN
DEVELOP IF THIS OCCURS. INHALATION: BREAT HING OF HIGH VAPOR
CONCENTRATIONS MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
CONTINUED INHALATION MAY RESULT IN UNCONSCIOUSNESS & DEATH. CHRONIC
ABUSE HAS BEEN ASSOCIATED WITH IRREGULAR HEART RHYTH MS & POTENTIAL
CARDIAC ARREST.
Effects of Overexposure:IRRITATION. EARLY TO MODERATE CNS DEPRESSION
RESULTING IN DIZZINESS, LIGHT-HEADEDNESS, HEADACHE, NAUSEA AND LOSS
OF COORDINATION. SKIN: BURNING SENSATION AND A DRIED, CRACKED
APPEARANCE. INGESTION: SE RIOUS LUNG DAMAGE AND FATAL CHEMICAL
PNEUMONITIS.

First Aid:EYE: FLUSH EYES WITH WATER WHILE HOLDING EYELIDS OPEN. REST
EYES FOR 30 MINUTES. CONSULT PHYSICIAN IF NEEDED. SKIN: WIPE OFF
EXCESS MATEIRAL FROM EXPOSED AREA. FLUSH SKIN WITH WATER. FOLLOW BY
WASH ING WITH SOAP IF AVAILABLE. GET MEDICAL ATTENTION AS NEEDED.
INHALATION: REMOVE VICTIM TO FRESH AIR. IF THE VICTIM HAS
DIFFICULTY BREATHING OR TIGHTNESS OF THE CHEST, IS DIZZY, VOMITING
OR UNRESPONSIV E, GIVE 100% OXYGEN WITH RESCUE BREATHING OR CPR AS
REQUIRED AND TRANSPORT TO THE NEAREST MEDICAL FACILITY. INGESTION:
DO NOT INDUCE VOMITING. RINSE VICTIM'S MOUTH. GET MEDICAL ADVISE.

Flash Point Method:SCC
Flash Point:=-7.2C, 19.F
Lower Limits:1
Upper Limits:8
Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL OR CO2.
Fire Fighting Procedures:DO NOT USE DIRECT STREAM OF WATER. WARNING
FLAMMABLE. CLEAR FIRE AREA OF UNPROTECTED PERSONNEL. DO NOT ENTER
CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR(HELMET WITH FACE
SHIELD, BUNKER COAT, GLOVES, RUBBER BOOTS), INCLUDING A POSITIVE
PRESSURE, NIOSH APPROVED, SELF- CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:CONTAINERS EXPOSED TO INTENSE HEAT FROM
FIRES SHOULD BE COOLED WITH WATER TO PREVENT WEAKENING OF CONTAINER
STRUCTURE WHICH COULD RESULT IN CONTAINER RUPTURE. VAPORS ARE
FLAMMABLE AND HEAVIER THAN AIR .AND MAY TRAVEL TO REMOTE IGNITION
SOURCE AND FLASH BACK.

Spill Release Procedures:SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE
AND CONTAIN SPILL. USE WATER SPRAY(FOG) TO REDUCE VAPORS OR DIVERT
VAPOR CLOUD DRIFT. IF VAPOR CLOUD FORMS, USE WATER FOG TO SUPRESS
OR BLANKET SPILL ARE A WITH FOAM. REMOVE WITH VACUUM TRUCK OR PUMP
TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH
AS CLAY, SAND OR SUITABLE MATERIAL AND DISPOSE OF PROPERLY. FLUSH
AREA WITH WATER.
Neutralizing Agent:THIS MATERIAL IS COVERED BY CERCLA PETROLEUM
EXCLUSION.

Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. GROUND FIXED EQUIPMENT. STATIC ELECTRICITY MAY ACCUMULATE AND
CREATE A FIRE HAZARD. SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE
LIQUID MATERIAL. VAPORS ARE FL AMMABLE AND HEAVIER THAN AIR. VAPORS
MAY TRAVEL ACROSS THE GROUND AND REACH REMOTE (BELOW)
Other Precautions:HANDLING CONT: IGNITION SOURCES CAUSING A FLASHBACK
FIRE DANGER. KEEP AWAY FROM HEAT, SPARKS AND FLAME. EXTINGUISH
PILOT LIGHTS, CIGARETTES AND TURN OFF OTHER SOURCES OF IGNITION
PRIOR TO USE AND UNTI L ALL VAPORS HAVE DISSIPATED. USE
EXPLOSION-PROOF VENTILATION TO PREVENT VAPOR ACCUMULATION WHILE IN
USE.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS TO A LEVEL WHICH IS ADEQUATE TO PROTECT WORKER
HEALTH, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR SELECTION,
USE AND MAINTENANCE SH OULD BE IN ACCORDANCE WITH REQUIREMENTS OF
OSHA RESPIRATORY PROTECTION STANDARD, 29CFR1910.134.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:NITRIL RUBBER GLOVES
Eye Protection:SAFETY GLASSES OR CHEMICAL GOGGLES.
Other Protective Equipment:USE PROTECTIVE CLOTHING WHICH IS CHEMICAL
RESISTANT TO THIS MATERIAL. SELECTION OF PROTECTIVE CLOTHING
DEPENDS ON POTENTIAL EXPOSURE CONDITIONS AND MAY INCLUDE GLOVES,
BOOTS, SUITS AND OTHER ITEMS.
Supplemental Safety and Health
THIS IS THE NEW NAME FOR TOLU-SOL W HT SOLVENT PER SHELL.

HCC:F2
Boiling Pt:B.P. Text:209-230F
Vapor Pres:40 MMHG@ 68F
Vapor Density:3.3
Spec Gravity:0.7399 @60F
VOC Grams/Liter:6.1
Evaporation Rate & Reference:3.2 (NBUAC=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT COLORED LIQUID; HYDROCARBON ODOR

Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:PREVENT VAPOR ACCUMULATION. AVOID HEAT,
SPARKS, FLAME AND OTHER IGNITION SOURCES.
Hazardous Decomposition Products:CARBON MONOXIDE AND UNIDENTIFIED
ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION.

Waste Disposal Methods:UNDER EPA-RCRA (40CFR 261) IF THIS MATERIAL
BECOMES A WASTE MATERIAL, IT WOULD BE AN IGNITABLE HAZARDOUS WASTE,
HAZARDOUS WASTE NUMBER D001. REFER TO THE LATEST EPA OR STATE
REGULATIONS REGARDING PROP ER DISPOSAL.

Toxicological Information:INHALATION LC50- 15,000 PPM (V) (RAT) 4
HOUR(S). DERMAL LD50- >2.84 G/KG (RAT). ORAL LD50- >7.1 G/KG
(RAT). EYE IRRITATION: MINIMAL IRRITATION (RABBIT), MATERIAL
TESTED- SOLVENT NAPHTHA, LIGHT ALIP HATIC. SKIN IRRITATION:
MINIMALLY IRRITATING, MATERIAL TESTED- HYDROCARBON SOLVENT.
SUBCHRONIC TESTING: WHILE THERE IS NO EVIDENCE THAT INDUSTRIALLY
ACCEPTABLE LEVELS OF LIGHT HYDROCARBON VAPORS (E. G., THE
OCCUPATIONAL EXPOSURE LIMIT) HAVE PRODUCED CARDIAC EFFECTS IN
HUMANS, ANIMAL STUDIES HAVE SHOWN THAT INHALATION OF HIGH LEVELS
PRODUCED CARDIAC SENSITIZATION. *SEE OTHER INFORMATION SECTION

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THIS SECTION WILL BE UPDATED AS ECOLOGICAL REVIEWS ARE
COMPLETED.

Transport Information:PROPER SHIPPING NAME: PETROLEUM DISTILLATES, NOS.
TECHNICAL NAME: PETROLEUM NAPHTHA. UN1268, HAZARD CLASS 3
(FLAMMABLE LIQUID), PACKING GROUP II. OIL: THIS MATERIAL IS AN
'OIL' UNDER 49 CFR PART 130 WHEN TRANSPORTED IN A CONTAINER OF
3500 GALLON CAPACITY OR GREATER. EMERGENCY RESPONSE GUIDE #128.

SARA Title III Information:SARA HAZARD CATEGORIES (311/312): FIRE
HAZARD. DELAYED (CHRONIC) HEALTH HAZARD.
Federal Regulatory Information:RESOURCE CONSERVATION AND RECOVERY ACT
(RCRA) CLASSIFICATION: D001 (IGNITABLE HAZARDOUS WASTE).
State Regulatory Information:CALIFORNIA SAFE DRINKING WATER AND TOXIC
ENFORCEMENT ACT (PROPOSITION 65): TOLUENE (108-88-3), <1 %WEIGHT,
THE CHEMICAL IDENTIFIED IS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER R EPRODUCTIVE HARM. NEW JERSEY
RIGHT-TO-KNOW CHEMICAL LIST: HEPTANE (142-82-5), 18% WEIGHT.
PENNSYLVANIA RIGHT-TO-KNOW CHEMICAL LIST: HEPTANE (142-82-5), 18%
WEIGHT.